Nuclear monobromination of alkyl phenyl ethers with NaClO2, NaBr, Mn(acac)3, and moist silica gel in aprotic solvent

Article abstract of DOI:10.1080/00397919808006845

Nuclear monobromination of aromatic ethers can be achieved with a NaClO₂/NaBr/Mn(acac)₃ catalyst/silica gel system in dichloromethane in regioselective and high-yielding manner under mild conditions.

Full text of DOI:10.1080/00397919808006845

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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Nuclear Monobromination
of Alkyl Phenyl Ethers with
NaClO2, NaBr, Mn(acac)3, and
Moist Silica Gel in Aprotic
Solvent
Masao Hirano a , Hiroyuki Monobe a , Shigetaka
Yakabe a & Takashi Morimoto a
a Department of Applied Chemistry , Faculty of
Technology, Tokyo University of Agriculture and
Technology , Koganei, Tokyo, 184, Japan
Published online: 22 Aug 2006.
To cite this article: Masao Hirano , Hiroyuki Monobe , Shigetaka Yakabe & Takashi
Morimoto (1998) Nuclear Monobromination of Alkyl Phenyl Ethers with NaClO2, NaBr,
Mn(acac)3, and Moist Silica Gel in Aprotic Solvent, Synthetic Communications: An
International Journal for Rapid Communication of Synthetic Organic Chemistry, 28:8,
1463-1470, DOI: 10.1080/00397919808006845
To link to this article: http://dx.doi.org/10.1080/00397919808006845
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