Bulletin of the Chemical Society of Japan p. 345 - 346 (1982)
Update date:2022-08-11
Topics:
Yamamoto, Jiro
Murakami, Mitushige
Kameoka, Noriaki
Otani, Norio
Umezu, Masahiro
Matsuura, Teruo
A 1:1 complex of pyridine N-oxide or trimethylamine oxide with SbCl5 acted as an oxidizing agent to benzyl alcohol, benzoin, furoin, and thiophenols more easily than via the oxides to give benzaldehyde, benzil, furil, and the corresponding disulfides respectively.The trimethylamine oxide-SbCl5 also oxidized p-xylene to p-tolualdehyde under nitrogen and to p-toluic acid under air.
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Doi:10.1039/c2ta00204c
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