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Cinnamaldehyde 104-55-2 /manufacturer/low price/high quality/in stock
Cas No: 104-55-2
USD $ 12.0-13.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
Cinnamic aldehyde 104-55-2 Direct Manufacturer
Cas No: 104-55-2
USD $ 3.0-3.5 / Kilogram 1 Kilogram 2000 Metric Ton/Year Xiamen BaiFuchem Co.,Ltd Contact Supplier
High quality Cinnamic Aldehyde supplier in China
Cas No: 104-55-2
No Data 1 Kilogram 200 Metric Ton/Year Simagchem Corporation Contact Supplier
China Manufacturer Supply Cinnamaldehyde CAS 104-55-2
Cas No: 104-55-2
No Data 1 Kilogram 1000 Kilogram/Year HANWAYS CHEMPHARM CO.,LIMITED Contact Supplier
Cinnamaldehyde, Cinnamic aldehyde, CAS: 104-55-2, 3-Phenyl-2-Propenal
Cas No: 104-55-2
No Data 1 Metric Ton Metric Ton/Day Nanjing Yuance Industry&Trade Co., Ltd. Contact Supplier
104-55-2 food grade cinnamyl aldehyde cinnamaldehyde 99%
Cas No: 104-55-2
USD $ 3.9-3.9 / Kilogram 1 Kilogram 10 Metric Ton/Day Baicao Pharmaceutical Co., Ltd. Contact Supplier
Cinnamaldehyde CAS 104-55-2
Cas No: 104-55-2
No Data No Data No Data Shanghai Sunwise Chemical Co., Ltd Contact Supplier
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Cas No: 104-55-2
USD $ 2.0-5.0 / Gram 1 Gram 99999 Kilogram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
Cinnamaldehyde
Cas No: 104-55-2
USD $ 12.0-12.0 / Gram 100 Gram 100 Metric Ton/Year Jinan Finer Chemical Co., Ltd Contact Supplier
Cinnamaldehyde
Cas No: 104-55-2
USD $ 1300.0-1300.0 / Gram 10000 Gram 10 Metric Ton/Month Hebei yanxi chemical co.,LTD. Contact Supplier

104-55-2 Usage

Occurrence

Reported found in celery seed, cinnamon, cinnamon leaf, cassia leaf, clove stem and lemon balm.

Potential Exposure

Botanical fungicide and insecticide. Used as an antifungal agent, corn rootworm attractant, and dog and cat repellent. Can be used on soil casing for mushrooms, row crops, turf, and all food commodities. Not listed for use in EU countries.

Contact allergens

This perfumed molecule is used as a fragrance in perfumes, a flavoring agent in soft drinks, ice creams, dentifrices, pastries, chewing-gum, etc. It can induce both contact urticaria and delayed-type reactions. It can be responsible for dermatitis in the perfume industry or in food handlers. Cinnamic aldehyde is contained in “fragrance mix.” As a fragrance allergen, it has to be mentioned by name in cosmetics within the EU.

Chemical Properties

Cinnamaldehyde exists as yellowish to greenish-yellow oily liquid with a Strong pungent, spicy, cinnamon odor. It is normally insoluble in water and many organic solvents but is miscible with alcohol and other flavoring oils. Exposure to air will result in thickening and oxidation. Cinnamaldehyde (cinnamic aldehyde, benzylideneactaldehyde, phenylacrolein, 3-phenylpropenal, 3-phenyl-2-propenal) is a saturated aldehyde with an aromatic ring that is a yellowish, oily liquid at room temperature. It is used as a flavoring and aromatic agent in a variety of food products, perfumes, and household products. It has also seen use as a rubber reinforcing agent. A burning taste that produces the odor and flavor of the spice may be found with this aromatic aldehyde. Cinnamaldehyde has also been used as an attractant for insect control, in the preparation of corrosion inhibitors, and as a coating for metals. Although extensively used in industry, it is also a natural constituent of cinnamon leaves and bark, some essential oils, and other plant products.

General Description

Yellow oily liquid with a cinnamon odor and sweet taste.

Anticancer Research

This is promising in antitumor activity against NSCLC cells. The cells were inducedin apoptosis and also the epithelial-mesenchymal transition was reversed affectingthe Wnt/b-catenin pathway (Bouyahya et al. 2016).

Reactivity Profile

Cinnamaldehyde reacts with sodium hydroxide owing to aerobic oxidation.

Taste threshold values

Taste characteristics at 0.5 ppm: spicy, cinnamon and cinnamon bark.

Health Hazard

Cinnamaldehyde can cause moderate to severeskin irritation. Exposure to 40 mg in48 hours produced a severe irritation effecton human skin. The toxicity of this compoundwas low to moderate on test subjects,depending on the species and the toxicroutes. However, when given by oral routein large amounts, its poisoning effect wassevere. Amounts greater than 1500 mg/kghave produced a wide range of toxic effectsin rats, mice, and guinea pigs. The symptomswere respiratory stimulation, somnolence,convulsion, ataxia, coma, hypermotility, anddiarrhea.LD50 value, oral (guinea pigs): 1150 mg/kgCinnamaldehyde is a mutagen. Its carcinogeniceffect is not established.

Agricultural Uses

Fungicide, Insecticide: Used as an antifungal agent, corn rootworm attractant, and dog and cat repellent. Can be used on soil casing for mushrooms, row crops, turf and all food commodities. Not listed for use in EU countries.

Uses

Cinnamic aldehyde is a common ingredient in perfumes for household products like deodorizers, detergents, and soap; flavor in toothpaste, sweets, ice cream, soft drinks, chewing gums, and cakes; in balsam of Tolu and Peru, hyacinth plant, spices, cinnamon, Ceylon and cassia oil; some perfumery uses (Canoe; hyacinth; bubblegum; Balsam; Cassia); natural occurrence (cinnamon).

Shipping

UN1989 Aldehydes, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid

Uses

In the flavor and perfume industry.

Uses

Cinnamaldehyde is used in flavor and perfumes.It occurs in cinnamon oils.

Trade name

ADIOS?; ZIMTALDEHYDE?; ZIMTALDEHYDE? LIGHT

Safety Profile

Poison by intravenous and parenteral routes. Moderately toxic by ingestion and intraperitoneal routes. A severe human skin irritant. Mutation data reported. Combustible liquid. May ipte after a delay period in contact with NaOH. When heated to decomposition it emits acrid smoke and fumes. See also ALDEHYDES.

Fire Hazard

Cinnamaldehyde is combustible.

Description

Cinnamic aldehyde is used as a flavoring agent, ingredient of fragrance in soft drinks, ice creams, dentifrices, pastries, chewing-gum, etc. It can induce both contact urticaria and delayed-type reactions. It can be implicated in contact dermatitis in those who work in the perfume industry or food handlers. Cinnamic aldehyde is contained in the "fragrance mix".

Chemical Synthesis

By isolation from natural sources; synthetically, by condensation of benzaldehyde with acetaldehyde in the presence of sodium or calcium hydroxide.

Incompatibilities

Aldehydes are frequently involved in selfcondensation or polymerization reactions. These reactions are exothermic; they are often catalyzed by acid. Aldehydes are readily oxidized to give carboxylic acids. Flammable and/or toxic gases are generated by the combination of aldehydes with azo, diazo compounds, dithiocarbamates, nitrides, and strong reducing agents. Aldehydes can react with air to give first peroxo acids, and ultimately carboxylic acids. These autoxidation reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). The addition of stabilizers (antioxidants) to shipments of aldehydes retards autoxidation. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, ketones, azo dyes, caustics, boranes, hydrazines

Air & Water Reactions

Thickens on exposure to air. May be unstable to prolonged exposure to air. Slightly water soluble .

Waste Disposal

Incineration. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers.

Aroma threshold values

Detection at 50 to 750 ppb.
InChI:InChI=1/C9H8O/c10-8-4-7-9-5-2-1-3-6-9/h1-8H/b7-4-

104-55-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name Cinnamaldehyde

1.2 Other means of identification

Product number -
Other names Cinnamyl aldehyde

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:104-55-2 SDS

104-55-2Synthetic route

3-Phenylpropenol
104-54-1

3-Phenylpropenol

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With dimethyl selenoxide In dichloromethane for 7h; Heating;100%
With 2,2'-bipyridylchromium peroxide In benzene for 1.25h; Heating;100%
With tert.-butylhydroperoxide; polystyrene-bound phenylselenic acid In tetrachloromethane for 63h; Heating;100%
cinnamyl-1,3-dithiane
26958-41-8

cinnamyl-1,3-dithiane

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With ammonium iodide; dihydrogen peroxide; sodium dodecyl-sulfate In water at 20℃; for 1h; micellar medium;100%
With dimethyl sulfoxide at 20℃; for 1h; Reagent/catalyst; Solvent;94%
With dihydrogen peroxide; iodine; sodium dodecyl-sulfate In water at 20℃; for 1h; Micellar solution;92%
3,3-diethoxyl-1-phenylprop-1-ene
7148-78-9

3,3-diethoxyl-1-phenylprop-1-ene

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With water at 20℃; for 2h;100%
With boron trifluoride diethyl etherate; tetraethylammonium iodide In chloroform for 2h; Heating;81%
With sulfuric acid In nitromethane for 48h; Ambient temperature; Yield given;
2-((E)-Styryl)-[1,3]dioxolane
83977-12-2, 5660-60-6

2-((E)-Styryl)-[1,3]dioxolane

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With water at 20℃; for 2h;100%
With n-butyltriphenylphosphonium peroxodisulfate In acetonitrile for 1h; Heating;97%
With tetrachlorosilane In dichloromethane at 20℃; for 0.25h;96%
(2E)-3-phenyl-2-propen-1-ol
4407-36-7

(2E)-3-phenyl-2-propen-1-ol

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With iodosylbenzene; 4 A molecular sieve; sodium ruthenate(VI) In dichloromethane at 20℃; for 3h; Oxidation;100%
With N-methyl-2-indolinone; tetrapropylammonium perruthennate; 1-ethyl-3-methylimidazolium hexafluorophosphate In dichloromethane at 20℃; for 1h;95%
With N-Bromosuccinimide; β‐cyclodextrin In methanol; water; acetone at 20℃; for 8h;94%
3-phenyl-propionaldehyde
104-53-0

3-phenyl-propionaldehyde

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With (2S)-2-{diphenyl[(trimethylsilyl)oxy]methyl}pyrrolidine; 2,3-dicyano-5,6-dichloro-p-benzoquinone In tetrahydrofuran at 20℃; for 1h;100%
With bis(benzonitrile)palladium(II) dichloride; tert.-butylnitrite; oxygen; toluene-4-sulfonic acid; 1,3,5-trimethyl-benzene In tert-butyl alcohol at 25℃; under 760.051 Torr; for 7h;94%
With manganese(IV) oxide; benzyl-methyl-amine; 2,3-dicyano-5,6-dichloro-p-benzoquinone In tetrahydrofuran at 20℃; for 6h; Reagent/catalyst; Solvent;78%
cinnamaldehyde dimethylacetal
4364-06-1

cinnamaldehyde dimethylacetal

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With water at 20℃; for 2h;100%
With iron(III) p-toluenesulfonate hexahydrate In water at 20℃; for 4h;96%
2-hydroxy-4-phenyl-3-butenenitrile
61912-03-6

2-hydroxy-4-phenyl-3-butenenitrile

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With (η(6)-benzene)chloro[1,2-bis(diphenylphosphino)ethane]ruthenium(II) chloride In benzene at 120℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube;100%
cinnamonitrile
4360-47-8

cinnamonitrile

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With potassium carbonate In water; dimethyl sulfoxide at 60℃; for 6h; High pressure; Green chemistry;99.9%
With formic acid; platinum(IV) oxide In water at 55 - 60℃; for 20h;56%
1,1-diacetoxy-3-phenylprop-2-ene
37973-54-9, 64847-78-5

1,1-diacetoxy-3-phenylprop-2-ene

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With tin(ll) chloride In acetonitrile at 25℃; for 0.0333333h; Hydrolysis;99%
With pyrographite In dichloromethane for 0.25h; Heating;98%
With iron(II) sulfate In dichloromethane for 0.25h; Heating;98%
iodobenzene
591-50-4

iodobenzene

(E)-3-(tri-n-butylstannyl)-2-propenal
81925-30-6, 149538-53-4, 219726-39-3

(E)-3-(tri-n-butylstannyl)-2-propenal

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With Pd-NHC star polymer P3 In d7-N,N-dimethylformamide at 20℃; for 19h; Stille Cross-Coupling (Migita-Kosugi-Stille Coupling);99%
2-styryl-benzo[1,3]dithiole
68498-19-1

2-styryl-benzo[1,3]dithiole

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With tetrafluoroboric acid; mercury(II) oxide In tetrahydrofuran for 5h; Ambient temperature;98%
cinnamaldoxime
13372-81-1

cinnamaldoxime

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With 1H-imidazole; [bis(acetoxy)iodo]benzene; Cu(AAOPD) In acetonitrile at 20℃; for 0.166667h;98%
With benzyltriphenylphosphonium dichromate In acetonitrile for 0.333333h; Oxidation; Heating;97%
With 1,4-dibenzyl-1,4-diazoniabicyclo[2.2.2]octane chlorochromate In acetonitrile for 0.25h; Heating;95%
trimethylsilyl cinnamyl ether
109283-53-6, 141427-94-3, 18042-41-6

trimethylsilyl cinnamyl ether

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With n-butyltriphenylphosphonium peroxodisulfate In acetonitrile for 0.166667h; Heating;98%
With manganese(IV) oxide; aluminium trichloride In acetonitrile for 0.25h; Oxidation; Heating;93%
With N-benzyl-N,N-dimethyl anilinium peroxodisulfate In acetonitrile for 0.116667h; Reflux;93%
5,5-Dimethyl-2-((E)-styryl)-[1,3]dioxane

5,5-Dimethyl-2-((E)-styryl)-[1,3]dioxane

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With sodium perborate In acetic acid at 25℃; for 8h;98%
With iron(III) p-toluenesulfonate hexahydrate In water for 1h; Reflux;74%
With water at 80℃; for 24h;17%
2-styryl-1,3-oxathiolane
80563-94-6

2-styryl-1,3-oxathiolane

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With N-Bromosuccinimide; water In acetone at 20℃; for 1.66667h; Hydrolysis;98%
With Glyoxilic acid; Amberlyst 15 for 0.025h; microwave irradiation;93%
Stage #1: 2-styryl-1,3-oxathiolane In ethanol at 20℃;
Stage #2: With water In ethanol at 20℃;
86%
2-((E)-Styryl)-[1,3]dioxane
5663-34-3

2-((E)-Styryl)-[1,3]dioxane

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With iron(III) chloride hexahydrate; acetaldehyde In dichloromethane at 20℃; for 0.25h;98%
3-phenyl-2-propenyl tetrahydro-2H-pyran-2-yl ether
99441-44-8, 80356-15-6

3-phenyl-2-propenyl tetrahydro-2H-pyran-2-yl ether

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With chromium(VI) oxide; HZSM-5 zeolite for 0.0166667h; microwave irradiation;95%
With aluminium trichloride; tetramethylammonium chlorochromate In acetonitrile for 0.916667h; Heating;92%
With zinc dichromate(VI) at 20℃;90%
1,1-dipropionyloxy-3-phenylprop-2-ene

1,1-dipropionyloxy-3-phenylprop-2-ene

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With tetra-N-butylammonium tribromide In methanol at 20℃; for 0.4h;95%
1,1-diisobutyryloxy-3-phenylprop-2-ene

1,1-diisobutyryloxy-3-phenylprop-2-ene

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With tetra-N-butylammonium tribromide In methanol at 20℃; for 1h;95%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

A

3-Phenyl-1-propanol
122-97-4

3-Phenyl-1-propanol

B

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With oxygen; potassium hydroxide In chloroform; water at 10℃; under 760.051 Torr; for 8h;A 5%
B 95%
With C28H37ClOOsP2; oxygen In toluene at 120℃; under 760.051 Torr; for 24h;
With phosphinito complex of palladium(II) In N,N-dimethyl-formamide at 80℃; for 24h;A 6 %Spectr.
B 24 %Spectr.
cinnamyl chloride
2687-12-9

cinnamyl chloride

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With 1-dodecyl-3-methylimidazolium iron chloride; periodic acid at 30℃; for 2h;94%
With water; sodium hydroxide at 20℃; for 0.0833333h; Microwave irradiation;87%
With sodium periodate In dichloromethane at 40 - 50℃; Ionic liquid;85%
With trimethylamine-N-oxide In dichloromethane; dimethyl sulfoxide for 6h; -20 deg C to r.t.;60%
Multi-step reaction with 2 steps
1: 88 percent / dimethylformamide
2: 1.) PdCl2, NaCl, NaOAc; 2.) O2 / 1.) AcOH, reflux; 2.) CH3CN, irradiation λ=366 nm
View Scheme
2-styryl-1,3-dithiolane
5616-58-0

2-styryl-1,3-dithiolane

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With thionyl chloride; dihydrogen peroxide In acetonitrile at 25℃; for 0.0166667h;93%
With silica gel In neat (no solvent) at 20℃; for 0.05h;92%
With oxygen; 2,4,6-tris(p-chlorophenyl)pyrylium perchlorate In dichloromethane for 1h; Irradiation;41%
cinnamaldehyde oxime
59336-59-3

cinnamaldehyde oxime

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With quinolinium dichromate(VI) In acetonitrile for 1.5h; Heating;93%
With water In acetone for 0.025h; microwave irradiation;93%
With silica gel; iron(III) chloride for 0.00833333h; microwave irradiation;90%
1-Phenyl-2-propyn-1-ol
4187-87-5

1-Phenyl-2-propyn-1-ol

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
toluene-4-sulfonic acid; tetrabutylammonium perrhenate In dichloromethane for 2h; Ambient temperature;92%
With [Ag{μ2-N,S-(1,3,5-triaza-7-phosphaadamantane)=NP(=S)(OEt)2}]x[SbF6]x In water at 160℃; for 5h; Microwave irradiation;91%
With methanesulfonic acid; iron(II) chloride tetrahydrate In 1,2-dichloro-ethane at 60℃; for 3h; Meyer-Schuster Rearrangement;90%
1-phenylpropene
637-50-3

1-phenylpropene

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With tert.-butylhydroperoxide; Ru(2,4,13,15-tetraphenyl-1,5,12,16-tetraaza-tricyclo[14.2.2.06,11]eicosa-4,6(11),7,9,12-pentaene)Cl2 In acetonitrile at 20℃; for 3h; Reagent/catalyst; Irradiation;92%
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane; water Ambient temperature; Yield given;
cinnamaldehyde semicarbazone
3839-82-5

cinnamaldehyde semicarbazone

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With NTPPPODS In water; acetonitrile for 0.416667h; Reflux;92%
With bismuth(III) chloride; benzyltriphenylphosphonium peroxymonosulfate In acetonitrile for 2h; Heating;75%
With aluminium trichloride; benzyltriphenylphosphonium chlorochromate In acetonitrile for 1.5h; Heating;75%
(α-styryl)(ethoxy)carbene chromium pentacarbonyl

(α-styryl)(ethoxy)carbene chromium pentacarbonyl

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With hexamethylenetetramine; water In tetrahydrofuran at 20℃; for 24h;92%
(E)-styrylaldehyde oxime
21737-13-3

(E)-styrylaldehyde oxime

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With aluminium trichloride; 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane dichromate at 20℃; for 0.00722222h;92%
With 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane dichromate In dichloromethane for 0.00722222h; Irradiation;92%
2-thioxo-4-thiazolidinone
141-84-4

2-thioxo-4-thiazolidinone

3-phenyl-propenal
104-55-2

3-phenyl-propenal

5-(3-phenyl-allylidene)-2-thioxo-thiazolidin-4-on e
15328-87-7

5-(3-phenyl-allylidene)-2-thioxo-thiazolidin-4-on e

Conditions
ConditionsYield
With ammonium acetate; acetic acid In toluene Reflux;100%
With thiourea; urea at 110℃; for 0.1h; Knoevenagel condensation; Neat (no solvent);91%
With sodium hydroxide
4-methoxy-aniline
104-94-9

4-methoxy-aniline

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
piperidine In ethanol for 5h; Heating;100%
With magnesium sulfate In dichloromethane at 20℃;100%
In ethyl 2-hydroxypropionate; water at 20℃; for 0.025h;96%
N-Phenylhydroxylamine
100-65-2

N-Phenylhydroxylamine

3-phenyl-propenal
104-55-2

3-phenyl-propenal

cinnamaldehyde-(N-phenyl oxime )
37056-75-0, 1070670-27-7

cinnamaldehyde-(N-phenyl oxime )

Conditions
ConditionsYield
In chloroform at 0℃;100%
In water Ambient temperature;93%
ethylenediamine
107-15-3

ethylenediamine

3-phenyl-propenal
104-55-2

3-phenyl-propenal

N,N'-bis(styrylmethylene)ethane-1,2-diamine
3080-97-5

N,N'-bis(styrylmethylene)ethane-1,2-diamine

Conditions
ConditionsYield
In ethanol for 1h; Condensation; Heating;100%
With sodium hydrogen sulfate; silica gel for 0.0333333h; microwave irradiation;89%
In ethanol Reflux; Inert atmosphere; Schlenk technique;78%
aniline
62-53-3

aniline

3-phenyl-propenal
104-55-2

3-phenyl-propenal

N-(3-phenylallylidene)benzenamine
953-21-9

N-(3-phenylallylidene)benzenamine

Conditions
ConditionsYield
With zirconocene dichloride In dichloromethane at 40℃; Schlenk technique; Inert atmosphere;100%
With magnesium sulfate In dichloromethane at 20℃;100%
In ethyl 2-hydroxypropionate; water at 20℃; for 0.0666667h;98%
semicarbazide hydrochloride
563-41-7

semicarbazide hydrochloride

3-phenyl-propenal
104-55-2

3-phenyl-propenal

cinnamaldehyde semicarbazone
3839-82-5

cinnamaldehyde semicarbazone

Conditions
ConditionsYield
With acetic acid In water for 0.5h; Reflux;100%
With aluminum oxide In water; tert-butyl alcohol for 0.0833333h;90%
With ethanol
In ethanol
3-phenyl-propenal
104-55-2

3-phenyl-propenal

acetophenone
98-86-2

acetophenone

Conditions
ConditionsYield
Stage #1: acetophenone With sodium hydroxide In ethanol; water at 0 - 5℃;
Stage #2: 3-phenyl-propenal In ethanol; water
100%
With poly(N-vinylimidazole) In neat (no solvent) at 20℃; for 0.666667h; Aldol Condensation; Sonication; Green chemistry;92%
With sodium hydroxide In ethanol; water90%
3-phenyl-propenal
104-55-2

3-phenyl-propenal

3-phenyl-propionaldehyde
104-53-0

3-phenyl-propionaldehyde

Conditions
ConditionsYield
With formic acid; 3,7-dimethyl10-p-tolyl-5-deazaflavins at 120℃; for 25h;100%
With tri-n-butyl-tin hydride; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran Ambient temperature;99%
With 0.42C23H20N4O4*2Cl(1-)*Zn(2+)*10.16H2O*0.58Pd(2+)*0.58C23H20N4O4(1-); hydrogen In tetrahydrofuran at 20℃; under 760.051 Torr; for 1h;99%
3-phenyl-propenal
104-55-2

3-phenyl-propenal

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With diphenylsilane; cesium fluoride at 25℃; for 0.05h;100%
With C28H28Cl2N4Pd; hydrogen In methanol at 30 - 35℃; under 760.051 Torr; for 8h; chemoselective reaction;100%
With C8H15BN2OS2; scandium tris(trifluoromethanesulfonate) In dichloromethane at 20℃; Reagent/catalyst; Schlenk technique; Inert atmosphere;100%
acetic anhydride
108-24-7

acetic anhydride

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Acetic acid 1-phenylsulfanylmethyl-but-2-ynyl ester

Acetic acid 1-phenylsulfanylmethyl-but-2-ynyl ester

Conditions
ConditionsYield
With pyridine; dmap100%
5-chloro-1H-indole-2-carbohydrazide
20948-67-8

5-chloro-1H-indole-2-carbohydrazide

3-phenyl-propenal
104-55-2

3-phenyl-propenal

5-Chlor-N'-(styrylmethylen)-2-indolcarbohydrazid
97132-94-0

5-Chlor-N'-(styrylmethylen)-2-indolcarbohydrazid

Conditions
ConditionsYield
In ethanol for 3h; Heating;100%
ethylene glycol
107-21-1

ethylene glycol

3-phenyl-propenal
104-55-2

3-phenyl-propenal

2-((E)-Styryl)-[1,3]dioxolane
83977-12-2, 5660-60-6

2-((E)-Styryl)-[1,3]dioxolane

Conditions
ConditionsYield
aluminum oxide In tetrachloromethane for 24h; Heating;100%
With natural kaolinitic clay In benzene for 2h; Heating;93%
With cationite KU-2 (H+) In water; benzene at 80℃; Dean-Stark;90%
thiosemicarbazide
79-19-6

thiosemicarbazide

3-phenyl-propenal
104-55-2

3-phenyl-propenal

cinnamaldehyde thiosemicarbazone
5351-70-2

cinnamaldehyde thiosemicarbazone

Conditions
ConditionsYield
With acetic acid In water for 0.5h; Reflux;100%
In methanol90%
With hydrogenchloride In ethanol at 20℃; for 3h;90%
1.3-propanedithiol
109-80-8

1.3-propanedithiol

3-phenyl-propenal
104-55-2

3-phenyl-propenal

cinnamyl-1,3-dithiane
26958-41-8

cinnamyl-1,3-dithiane

Conditions
ConditionsYield
With thionyl chloride; silica gel In benzene at 20℃; for 5h;100%
tellurium tetrachloride In 1,2-dichloro-ethane for 3h; Ambient temperature;99%
With lithium trifluoromethanesulfonate at 90℃; for 0.0833333h; Alkylation;98%
3-bromo-3,3-difluropropene
420-90-6

3-bromo-3,3-difluropropene

3-phenyl-propenal
104-55-2

3-phenyl-propenal

4,4-difluoro-1-phenylhexa-1,5-dien-3-ol
88257-89-0

4,4-difluoro-1-phenylhexa-1,5-dien-3-ol

Conditions
ConditionsYield
With indium In water at 20℃; for 3h; Addition;100%
With zinc In tetrahydrofuran 1.) 0 deg C to RT, 4.5 h; 2.) RT, overnight;74%
3-(benzimidazol-2-ylmethyl)thiazolidine-2,4-dione
105192-15-2

3-(benzimidazol-2-ylmethyl)thiazolidine-2,4-dione

3-phenyl-propenal
104-55-2

3-phenyl-propenal

3-(1H-Benzoimidazol-2-ylmethyl)-5-[(E)-3-phenyl-prop-2-en-(E)-ylidene]-thiazolidine-2,4-dione
105192-22-1

3-(1H-Benzoimidazol-2-ylmethyl)-5-[(E)-3-phenyl-prop-2-en-(E)-ylidene]-thiazolidine-2,4-dione

Conditions
ConditionsYield
With sodium acetate In acetic acid for 12h; Heating;100%
3-phenyl-propenal
104-55-2

3-phenyl-propenal

phenylhydrazine
100-63-0

phenylhydrazine

cinnamaldehyde phenylhydrazone
1216-15-5

cinnamaldehyde phenylhydrazone

Conditions
ConditionsYield
piperidine In ethanol for 5h; Heating;100%
With oxidized single-walled carbon nanotubes(SWCNs-COOH) In ethanol at 80℃; for 0.75h;98%
With Dowex resin acid form In ethanol for 0.75h;88%
3-phenyl-propenal
104-55-2

3-phenyl-propenal

1-methyl-1-aminoguanidinium iodide

1-methyl-1-aminoguanidinium iodide

N-Diaminomethylene-N-methyl-N'-[(E)-3-phenyl-prop-2-en-(E)-ylidene]-diazenium; iodide

N-Diaminomethylene-N-methyl-N'-[(E)-3-phenyl-prop-2-en-(E)-ylidene]-diazenium; iodide

Conditions
ConditionsYield
In methanol at 20℃; for 336h;100%
3-phenyl-propenal
104-55-2

3-phenyl-propenal

benzylamine
100-46-9

benzylamine

1-benzyl-4-phenyl-1-aza-1,3-butadiene
77499-86-6, 99333-56-9, 119353-37-6, 60293-41-6

1-benzyl-4-phenyl-1-aza-1,3-butadiene

Conditions
ConditionsYield
With magnesium sulfate In dichloromethane at 20℃; for 6h; Schlenk technique; Inert atmosphere;100%
With 1-butyl-3-methylimidazolium Tetrafluoroborate In neat (no solvent) at 60℃; for 2h; Reagent/catalyst; Inert atmosphere; Electrolysis;95%
In methanol at 20℃; Molecular sieve;79%
3-phenyl-propenal
104-55-2

3-phenyl-propenal

methyl 2-cyanoacetate
105-34-0

methyl 2-cyanoacetate

2-cyano-5-phenyl-2,4-pentadien carboxylic acid methyl ester
85620-43-5

2-cyano-5-phenyl-2,4-pentadien carboxylic acid methyl ester

Conditions
ConditionsYield
aluminum oxide for 0.05h; Ambient temperature;100%
With diammonium phosphate In water at 20℃; Knoevenagel condensation;90%
With Porcine Pancreas Lipase In water; tert-butyl alcohol at 40℃; for 120h; Knoevenagel Condensation; Enzymatic reaction; stereoselective reaction;89%
With aluminum oxide; ammonium acetate for 0.0333333h; Knoevenagel condensation; microwave irradiation (850 watt);70%
3-phenyl-propenal
104-55-2

3-phenyl-propenal

α-chloro-cinnamaldehyde
18365-42-9

α-chloro-cinnamaldehyde

Conditions
ConditionsYield
With pyridine; Phenylselenyl chloride In dichloromethane at 37℃; for 96h;100%
Multi-step reaction with 2 steps
1: chloroform; chlorine
2: glacial acetic acid; potassium acetate
View Scheme
Multi-step reaction with 2 steps
1: carbon tetrachloride; chlorine / -5 °C
2: aqueous sodium acetate
View Scheme
benzaldehyde
100-52-7

benzaldehyde

3-phenyl-propenal
104-55-2

3-phenyl-propenal

2-((E)-Styryl)-[1,3]dioxolane
83977-12-2, 5660-60-6

2-((E)-Styryl)-[1,3]dioxolane

Conditions
ConditionsYield
With monoaluminum phosphate In acetonitrile for 1.5h; Heating;100%
3-phenyl-propenal
104-55-2

3-phenyl-propenal

(2E)-3-phenyl-2-propen-1-ol
4407-36-7

(2E)-3-phenyl-2-propen-1-ol

A

o-terphenyl
84-15-1

o-terphenyl

B

3,3-bis(3-phenyl-2-propen-1-yl)pentane-2,4-dione
106536-22-5

3,3-bis(3-phenyl-2-propen-1-yl)pentane-2,4-dione

C

C18H16

C18H16

Conditions
ConditionsYield
With triphenylphosphine; palladium(II) acetylacetonate In 1,4-dioxane for 91h; Heating;A 43%
B 100%
C n/a
With triphenylphosphine; palladium(II) acetylacetonate In 1,4-dioxane for 24h; Heating;A 16%
B 89%
C 37%
3-phenyl-propenal
104-55-2

3-phenyl-propenal

lithium tetrabutylindate

lithium tetrabutylindate

1-phenyl-1-hepten-3-ol
20157-19-1

1-phenyl-1-hepten-3-ol

Conditions
ConditionsYield
for 2h; Ambient temperature;100%
3-phenyl-propenal
104-55-2

3-phenyl-propenal

2-hydroxyethanethiol
60-24-2

2-hydroxyethanethiol

2-styryl-1,3-oxathiolane
80563-94-6

2-styryl-1,3-oxathiolane

Conditions
ConditionsYield
With PPA; silica gel In 1,2-dichloro-ethane at 20℃; for 0.5h;100%
TiCl4 on montmorillonite In dichloromethane for 1h; Heating;95%
bis(acetylacetonato)dioxidomolybdenum(VI) In acetonitrile at 20℃; for 3.5h;92%

104-55-2Related news

Platinum catalysed aerobic selective oxidation of Cinnamaldehyde (cas 104-55-2) to cinnamic acid08/11/2019

Aerobic selective oxidation of allylic aldehydes offers an atom and energy efficient route to unsaturated carboxylic acids, however suitable heterogeneous catalysts offering high selectivity and productivity have to date proved elusive. Herein, we demonstrate the direct aerobic oxidation of cinn...detailed

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