Tetrahedron Letters p. 2527 - 2528 (1986)
Update date:2022-08-17
Topics:
Bulman Page, Philip C.
Rosenthal, Stephen
α-Ketoacylsilanes may be prepared by the sequential osmium tetroxide catalysed dihydroxylation and Swern oxidation of cis-vinylsilanes.Addition of nucleophiles to α-ketoacylsilanes occurs to give products arising exclusively from reactions at the silicon-bearing carbonyl group.
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