Bulletin of the Chemical Society of Japan p. 513 - 520 (1988)
Update date:2022-08-31
Topics:
Ichikawa, Shuji
Tomita, Isao
Hosaka, Akira
Sato, Tadashi
Under UV irradiation in the presence of iron(III) chloride or iron (III) triflate in pyridine, D-glucose, D-mannose, and D-galactose underwent a selective bond cleavage at the C1-C2 position, producing 4-O-formyl-D-arabinopyranose and 4-O-formyl-D-lyxopyranose.D-Fructose, under the same conditions, gave arabino-γ-lactone.The reaction was interpreted in terms of the photoinduced electron transfer within a chelate of iron ion with the carbohydrate molecule.
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