Journal of Organic Chemistry p. 3371 - 3373 (1988)
Update date:2022-08-16
Topics:
Macdonald, Simon J. F.
Huizinga, Wouter B.
McKenzie, Thomas C.
Coupling reactions between glycopyranosyl fluorides and 2-(diethylaluminio)furan and 2-(diethylaluminio)-1-methylpyrrole giving the corresponding sugar heterocycles are observed to proceed with retention of configuration at the anomeric center.Couplings of the same aluminated heterocycles with ribofuranosyl fluorides gave predominantly the β-ribofuranosyl heterocycle.
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