Stereospecific Benzylic Hydroxylation of Bicyclic Alkenes by Pseudomonas putida: Isolation of (+)-R-1-Hydroxy-1,2-dihydronaphthalene, an Arene Hydrate of Naphthalene from Metabolism of 1,2-Dihydronaphthalene

DOI: 10.1039/c39890000339

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Journal of the Chemical Society. Chemical communications p. 339 - 341 (1989)

Update date:2022-08-17

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Authors:

Boyd, Derek R.

McMordie, R. Austin S.

Sharma, Narain D.

Dalton, Howard

Williams, Paul

Jenkins, Richard O.

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Article abstract of DOI:10.1039/c39890000339

Metabolism of the bicyclic alkenes 1,2-dihydronaphthalene, indene, and 1,2-benzocyclohepta-1,3-diene by a mutant strain of Pseudomonas putida yields benzylic monols (exclusively with R configuration) as metabolites and vicinal cis diols as minor products having an excess of the S configuration at the benzylic position.

Full text of DOI:10.1039/c39890000339

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