Methyl-jasmonat: Ein kurzer Weg zum Naturstoff und seinem unnatuerlichen Enantiomer via Palladium(0)-induzierte, enantiodivergente Alkylierung von Cyclopent-2-en-1,3-diol-Derivaten

DOI: 10.1002/hlca.19890720822

Source and publish data:

Helvetica Chimica Acta p. 1852 - 1859 (1989)

Update date:2022-08-17

Topics:

Authors:

Montforts, Franz-Peter

Gesing-Zibulak, Ingrid

Grammenos, Wassilios

Schneider, Manfred

Laumen, Kurt

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19890720822

Palladium-catalyzed alkylation of cyclopent-2-ene-1,2-diol derivatives like 2 is a useful method for enantiodivergent functionalization, resulting both enantiomeric series of chiral building blocks.The chiral building blocks 3 and 13 can be transformed to methyl-jasmonate (1) and its unnatural enantiomer ent-1, recent statement <1b> that 1 has no odour at all and that "methyl-jasmonate's" fragrance is actually due to its cis-isomer ent-11 has been confirmed also for the enantiomeric series.

Full text of DOI:10.1002/hlca.19890720822

Products guided by the article

Product name:Cyclopentaneacetic acid, 3-oxo-2-(2-pentenyl)-, methyl ester, (1R,2R)-rel-

Cas No:109959-42-4

R&D Labs maybe for 109959-42-4

Jiaxing Carry Bio-Chem Technology Co.,Ltd

website:http://www.carrybiotech.com

Contact:0573-82788958

Address:Add.Fl 3th, Pharm Vally,Kaichuang Rd, Xiuzhou District, Jiaxing, Zhejiang,314031,China
Suzhou Tianma Specialty Chemicals Co.,Ltd

Contact:+86-512-68090577

Address:#199, Huayuan Rd, Mudu, Suzhou, Jiangsu, CHINA
Hangzhou Keyingchem Co.,Ltd

website:http://www.keyingchem.com/

Contact:+86-571-85378921

Address:Jintong international Building, No.113,Huayuangang Street, Gong shu District, Hangzhou,Zhejiang, China.
Dongguan Albiya Energy Science and Technology Co.,Ltd

Contact:+86-769-22181286

Address:Huanan Industial Park, Dongguan,China
Tianjin Pharmacn Medical Technology Co.,Ltd.

Contact:86-22-60122566ext.866(English),23359620

Address:Green Industrial Base, 6 Haitaifazhan Sixth Rd., Huayuan Industrial Area, Tianjin, 300384, China

Relevant to this article

Design, synthesis, and anti-HIV activity of 2′,3′-didehydro-2′,3′-dideoxyuridine (d4U), 2′,3′-dideoxyuridine (ddU) phosphoramidate 'ProTide' derivatives

Doi:10.1016/j.bmcl.2007.04.043
(2007)
The structural and electronic impact on the photophysical and biological properties of a series of Cu^I and Ag^I complexes with triphenylphosphine and pyrimidine-type thiones

Doi:10.1039/c4nj02203c
(2015)
Identification of rice Os4BGlu13 as a β-glucosidase which hydrolyzes gibberellin A4 1-O-β-d-glucosyl ester, in addition to tuberonic acid glucoside and salicylic acid derivative glucosides

Doi:10.1016/j.abb.2015.07.021
(2015)
Iron and ruthenium heterobimetallic carbonyl complexes as electrocatalysts for alcohol oxidation: Electrochemical and mechanistic studies

Doi:10.1021/om101070z
(2011)
In vitro oxidative metabolism of 6-mercaptopurine in human liver: Insights into the role of the molybdoflavoenzymes aldehyde oxidase, xanthine oxidase, and xanthine dehydrogenase

Doi:10.1124/dmd.114.058107
(2014)
A phosphatase specific for nucleoside diphosphates.

Doi:10.1016/0006-3002(55)90275-4
(1955)

Article Doi