Journal of Fluorine Chemistry p. 213 - 224 (1989)
Update date:2022-08-30
Topics:
Napoli, M.
Conte, L.
Gambaretto, G. P.
Carlini, F. M.
Electrochemical fluorination of 4-(perfluoro-n-butyl)-n-butanoyl chloride produces perfluorooctanoyl fluoride in higher yields than those obtained from n-octanoyl chloride, which is the usual starting material.In particular, one of the by-products of the industrial process, the cyclic perfluoroether perfluoro-2-propyl-tetrahydropyran, is not formed.Also the other by-products, except fluorocarbon perfluoro-n-heptane, are produced in lower amounts.These results are discussed and a mechanism is suggested.
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