Palladium-catalyzed coupling of functionalized bromoarenes to a polystyrene-bound aryl tributylstannane

Article abstract of DOI:10.1016/S0040-4039(98)02384-3

The Stille reaction with a polystyrene-bound stannyl component, catalyzed by a palladacycle complex, provides a convenient and clean method for the synthesis of substituted biaryls on the resin. Several functional groups useful for the construction of supported polydentate amino alcohols were successfully introduced.