Tetrahedron Letters p. 5628 - 5631 (2015)
Update date:2022-08-02
Topics:
Shen, Hang
Zhang, Xiaohui
Liu, Qing
Pan, Jing
Hu, Wen
Xiong, Yan
Zhu, Xiangming
An environmentally benign and metal-free cyanation method of tertiary amines oxidated by hypervalent iodine(III) intermediate generated in situ from PIFA (or DIB) and TMSCN has been developed. A variety of substituent groups on amines are tolerated to the oxidation of α-C-H bond to form C-C bond in the absence of metal catalysts with yields of up to 74%.
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