Cationic bis(oxazoline)Cu(II) Lewis acid catalysts. Application to the asymmetric synthesis of ent-Δ1-tetrahydrocannabinol

DOI: 10.1016/S0040-4039(97)00609-6

Source and publish data:

Tetrahedron Letters p. 3193 - 3194 (1997)

Update date:2022-08-11

Topics:

Authors:

Evans, David A.

Shaughnessy, Eileen A.

Barnes, David M.

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Article abstract of DOI:10.1016/S0040-4039(97)00609-6

The Diels-Alder reaction of acryloyl oxazolidinone and 1-acetoxy-3-methylbutadiene is catalyzed by the cationic bis(oxazoline)Cu(II) complex 4 in high enantioselectivity. The cycloadduct is converted to ent-Δ¹-tetrahydrocannabinol (THC) in four

Full text of DOI:10.1016/S0040-4039(97)00609-6

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