PROTONATION OF 1-ARYL-3,3,3-TRIFLUOROPROPYNES

DOI: 10.1016/S0040-4039(00)99453-X

Source and publish data:

Tetrahedron Letters p. 1315 - 1318 (1989)

Update date:2022-08-11

Topics:

Authors:

Allen, Annette D.

Angelini, Giancarlo

Paradisi, Cristina

Stevenson, Andrew

Tidwell, Thomas T.

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Article abstract of DOI:10.1016/S0040-4039(00)99453-X

1-Aryl-3,3,3-trifluoropropynes (1) react in aqueous acid with ρ⁺= -6.5, and the gas phase basicity of 4-CH₃C₆H₄C<*>CH is 7.8 kcal/mol less favorable than that of 4-CH₃C₆H₄C<*>CH,

Full text of DOI:10.1016/S0040-4039(00)99453-X

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