Asymmetric Syntheses of (-)-Malyngolide and (-)-Frontalin by Utilizing Bakers' Yeast Reduction of S-Ethyl 2-Cyclopentanonecarboxylthioate

DOI: 10.1246/cl.1988.1739

Source and publish data:

Chemistry Letters p. 1739 - 1742 (1988)

Update date:2022-08-11

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Authors:

Sato, Toshio

Maeno, Hajime

Noro, Tomohiro

Fujisawa, Tamotsu

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Article abstract of DOI:10.1246/cl.1988.1739

Bakers' yeast reduction of S-ethyl 2-cyclopentanonecarboxylthioate affords optically pure S-ethyl (1R,2S)-2-hydroxycyclopentanecarboxylthioate which is stereoselectively converted into (-)-malyngolide and (-)-frontalin.

Full text of DOI:10.1246/cl.1988.1739

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