Chemistry Letters p. 977 - 980 (1980)
Update date:2022-08-11
Topics:
Tsuge, Otohiko
Sone, Kazuhiro
Urano, Sathoshi
The reaction of carbanions, prepared from 2-(trimethylsilylmethyl)pyridine or N,N-dimethyltrimethylsilylacetamide and lithium diisopropylamide in tetrahydrofuran, with α-aryl-N-phenylnitrones afforded a mixture of corresponding (E)-alkene, azobenzene and azoxybenzene, respectively.On the other hand, the carbanions reacted with cyclic nitrones to give the corresponding aziridine and/or hydroxylamine derivatives as major products.
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