Tetrahedron Letters p. 3107 - 3110 (1986)
Update date:2022-08-11
Topics:
Behforouz, Mohammad
Curran, Timothy T.
Bolan, Joseph L.
Mixed cuprates ArSCu(RMgX)n add rapidly to crotonates and cinnamates to give high yields of Michael adducts.Cuprates of methyl, ethyl, isopropyl, t-butyl, phenyl and vinyl were used.Crotonates give much higher yields of adducts with cuprates using 2-methoxythiophenoxide as a ligand than with those using thiophenoxide.
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