Journal of Organic Chemistry p. 3392 - 3398 (1991)
Update date:2022-08-16
Topics:
Shin, Jongheon
Fenical, William
Five new diterpenoids of the dolabellane class (3-7) have been isolated from the Caribbean gorgonian Eunicea laciniata Duchassaing and Michelotti.The structures of these metabolites were defined by combined spectra and chemical methods.The conformation and reactivity of the 11-membered ring of the dolabellanes was investigated by 1H NMR nuclear Overhauser enhancement difference spectroscopy (NOEDS) and by selected chemical transformations involving transannular cyclizations.
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