Thermochimica Acta p. 29 - 36 (2003)
Update date:2022-08-11
Topics:
Madhu
Radhakrishnan
Grunert, Matthias
Weinberger, Peter
Linert, Wolfgang
The phenomenological, kinetic and mechanistic aspects of thermal decomposition of perchlorate, nitrate, chloride, bromide and iodide complexes of cobalt(II) with the Schiff base 1,2-di(imino-4′-antipyrinyl)ethane (GA) have been studied by TG and DTG analyses. The kinetic parameters like the activation energy, pre-exponential factor and entropy of activation were calculated. The decomposition reactions follow random nucleation with one nucleus on each particle - Mampel model .
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