Journal of Structural Chemistry p. 835 - 839 (2016)
Update date:2022-08-17
Topics:
Bouchouit
Bouraiou
Bouacida
Belfaitah
Merazig
The preparation of a cobalt(II) chloride complex with a N-donor ligand 1-benzyl-5-methyl-1H-imidazole of formula [CoCl2(1-benzyl-5-methyl-1H-imidazole)2] is described. The isolated complex was characterized by UV, IR spectroscopy and crystallographic studies. Single crystal X-ray diffraction analysis of the complex reveals its monomeric tetra-coordinated nature. The coordination polyhedron around the cobalt center can be described as a quasi-regular tetrahedron. The Co–N distances for this compound are 2.0111(17) ? and 2.0118(17) ?, while the Co–Cl distances are 2.2582(7) ? and 2.2549(7) ?. The crystal packing can be described as layers parallel to (101) plane alternating along the b axis, and it is stabilized by π–π stacking between the imidazole and phenyl rings. The shortest centroid–centroid distance is 3.6002(14) ?.
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