Angewandte Chemie International Edition
10.1002/anie.201915747
COMMUNICATION
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To summarize, we have successfully created a new class of
Rh
Time-dependent study reveals that the formation of Rh
RNRs mainly involves the initial formation of Sb
transformation of Sb , the reduction of Rh species, and the
interdiffusion to form Rh Sb RNRs. The Rh Sb RNRs/C exhibit a
high NH
yield rate of 228.85 ± 12.96 µg h-1 mg-1Rh at -0.45 VRHE
in 0.5 M Na SO , outperforming Rh Sb SNRs/C and Rh NPs/C,
due to the enhanced adsorption and activation of N on high-
index facets of Rh Sb RNRs/C. Rh Sb RNRs/C also show
2
Sb RNRs with high-index facets for NRR for the first time.
Sb
the
2
2
3
O ,
2
O
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2
[
[
2
2
durable electrochemical stability with negligible activity decay
after continuous electrolysis for 10 h. The present work
demonstrates the important role of surface regulation of
catalysts in boosting NRR performance and provides a new
strategy for creating efficient NRR electrocatalysts.
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Acknowledgements
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This work was financially supported by the Ministry of Science
and Technology (2016YFA0204100, 2017YFA0208200), the
National Natural Science Foundation of China (21571135),
Young Thousand Talented Program, Natural Science
Foundation of Jiangsu Higher Education Institutions
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Keywords: Rh-Sb • Nanorod • Surface regulation • High-index
facet • Nitrogen reduction reaction
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