Journal of the Chemical Society. Chemical communications p. 1274 - 1276 (1989)
Update date:2022-08-11
Topics:
Bowen, Richard D.
Colburn, Alex W.
Derrick, Peter J.
In contrast to CH3CH2(CH3)C=O+CH3 and (CH3)2CHCH=O+CH3, which in slow dissociations lose mainly CH3OH, metastable CH3CH2CH2CH=O+CH3 expels predominantly CH2O by isomerising to CH3CH2CH2CH2+O=CH2, probably via two 1,2-H shifts and a subsequent 1,5-H shift; CH3CH2CH2CH2+O=CH2 undergoes limited interconversion with CH3+CHCH2CH2OCH3, prior to CH2O elimination, via a 1,5-H shift.
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