Journal of the Chemical Society. Chemical communications p. 1274 - 1276 (1989)
Update date:2022-08-11
Topics:
Bowen, Richard D.
Colburn, Alex W.
Derrick, Peter J.
In contrast to CH3CH2(CH3)C=O+CH3 and (CH3)2CHCH=O+CH3, which in slow dissociations lose mainly CH3OH, metastable CH3CH2CH2CH=O+CH3 expels predominantly CH2O by isomerising to CH3CH2CH2CH2+O=CH2, probably via two 1,2-H shifts and a subsequent 1,5-H shift; CH3CH2CH2CH2+O=CH2 undergoes limited interconversion with CH3+CHCH2CH2OCH3, prior to CH2O elimination, via a 1,5-H shift.
View MoreYingYing Pharmaceutical Co.,Ltd
Contact:86-18854126208
Address:55#, yingxiongshan road
Zibo Xiaoguang Chemical Material Co., Ltd
Contact:15954099116
Address:Boshan Development Zone
Contact:86-571-61063068
Address:LINAN
LIAONING DMSO CHEMICALS CO.,LTD.
website:http://www.chinadmso.com
Contact:+86-427-6503033
Address:FLOOR 16, BLOCK A, FINANCIAL SQUARE, XINGLONGTAI DISTRICT, PANJIN CITY, LIAONING P.R. CHINA
CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD
website:http://www.czyys.com
Contact:0086-519-88802789
Address:No.300,Yanling Middle Road, Changzhou, Jiangsu, China
Doi:10.1021/jp9932867
(2000)Doi:10.1039/tf9575300656
(1957)Doi:10.1039/d0tb00942c
(2020)Doi:10.2533/000942904777678127
(2004)Doi:10.1021/jo01255a057
(1969)Doi:10.1016/0022-328X(86)80099-7
(1986)
