Convenient preparation of 2-deoxy-3,5-di-O-p-toluoyl-α-D-erythro-pentofuranosyl chloride

Article abstract of DOI:10.1080/00397919708007071

By using acetyl chloride as HCl generator, the procedure for the Hoffer preparation of the α-chloro sugar 4a was significantly improved. The α-configuration of the chloro atom was confirmed by using NOE measurement. Sequential transformation of 4a to the β-anomer and to the furfuryl derivative 6 was studied.

Full text of DOI:10.1080/00397919708007071

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Synthetic Communications: An
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Organic Chemistry
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Convenient Preparation of 2-
Deoxy-3,5-di-O-p-toluoyl-α-
D-erythro-pentofuranosyl
Chloride
Valérie Rolland a , Mitsuharu Kotera a & Jean
Lhomme a
a LEDSS, UMR 5616, CNRS, BP53, Université Joseph
Fourier, 38041, GRENOBLE, France
Version of record first published: 22 Aug 2006.
To cite this article: Valérie Rolland, Mitsuharu Kotera & Jean Lhomme (1997):
Convenient Preparation of 2-Deoxy-3,5-di-O-p-toluoyl-α-D-erythro-pentofuranosyl
Chloride, Synthetic Communications: An International Journal for Rapid
Communication of Synthetic Organic Chemistry, 27:20, 3505-3511
To link to this article: http://dx.doi.org/10.1080/00397919708007071
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