SmI2-mediated reductive enolization of α-hetero-substituted ketones and enantioselective protonation

DOI: 10.1016/S0040-4039(97)00435-8

Source and publish data:

Tetrahedron Letters p. 2709 - 2712 (1997)

Update date:2022-08-11

Topics:

Authors:

Nakamura, Yutaka

Takeuchi, Seiji

Ohgo, Yoshiaki

Yamaoka, Makoto

Yoshida, Akihiro

Mikami, Koichi

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Article abstract of DOI:10.1016/S0040-4039(97)00435-8

High enantioselectivity (up to 94% ee) has been achieved in the protonation of samarium enolates which were generated by Sml₂-mediated reduction of 2-aryl-2-methoxycrclohexanones using a C₂-symmetric chiral diol as a proton source.

Full text of DOI:10.1016/S0040-4039(97)00435-8

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