SmI2-mediated reductive enolization of α-hetero-substituted ketones and enantioselective protonation

DOI: 10.1016/S0040-4039(97)00435-8

Source and publish data:

Tetrahedron Letters p. 2709 - 2712 (1997)

Update date:2022-08-11

Topics:

Authors:

Nakamura, Yutaka

Takeuchi, Seiji

Ohgo, Yoshiaki

Yamaoka, Makoto

Yoshida, Akihiro

Mikami, Koichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)00435-8

High enantioselectivity (up to 94% ee) has been achieved in the protonation of samarium enolates which were generated by Sml₂-mediated reduction of 2-aryl-2-methoxycrclohexanones using a C₂-symmetric chiral diol as a proton source.

Full text of DOI:10.1016/S0040-4039(97)00435-8

Products guided by the article

Product name:2-PHENYLCYCLOHEXANONE

Cas No:1444-65-1

R&D Labs maybe for 1444-65-1

Kono Chem Co.,Ltd

website:http://www.konochem.com

Contact:86-29-86107037

Address:No.170 West Avenue,Xi’an 710082,China
MiHecb Bio-Tech Co., Ltd.

Contact:+86-0592 5353131

Address:No.56 Guani Road Software Park 2,Siming District
Shanghai Egoal Chemical Co.,Ltd

Contact:+86-21-50333091

Address:Yangming Garden Square 3,YangGao North Road 1188, Pudong New District, Shanghai
CHEMINN LTD.

website:http://www.cheminn.com/

Contact:86-531-67875205

Address:No.9-2,South of Shanda Road, Jinan ,China
HENAN NEW BLUE CHEMICAL CO.,LTD

website:http://www.newbluechem.com

Contact:86-371-55170693/55170694

Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China

Relevant to this article

Doi:10.1021/ja01516a057
(1959)
Synthesis and biological evaluation of some new triazolo[1,5-a]quinoline derivatives as anticancer and antimicrobial agents

Doi:10.1039/c3ra46961a
(2014)
Comparison of the prevention of aflatoxin B₁-induced genotoxicity by quercetin and quercetin pentaacetate

Doi:10.1016/S0960-894X(02)00478-X
(2002)
Unveiling the role of ancillary ligands in acceptorless benzyl alcohol dehydrogenation and etherification mediated by mesoionic carbene iridium complexes

Doi:10.1039/c7dt04109h
(2018)
Activation of the NLRP3 Inflammasome by Hyaboron, a New Asymmetric Boron-Containing Macrodiolide from the Myxobacterium Hyalangium minutum

Doi:10.1021/acschembio.8b00659
(2018)
Doi:10.1021/ja00787a033
(1973)

Article Doi