Pentafluorophenyl Nitrene: a Matrix Isolated Aryl Nitrene that Does Not Undergo Ring Expansion

DOI: 10.1039/c39820001192

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1192 - 1193 (1982)

Update date:2022-08-30

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Authors:

Dunkin, Ian R.

Thomson, Paul C. P.

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Article abstract of DOI:10.1039/c39820001192

Photolysis of pentafluorophenyl azide or pentafluorophenyl isocyanate in low-temperature matrices gives pentaflurophenyl nitrene which, in the presence of CO, may react photochemically but not thermally to give the isocyanate.

Full text of DOI:10.1039/c39820001192

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