Selective preparation of 1,3-butadienyl phosphines, 1-iodo- and 1,4-diiodo-butadienyl phosphine oxides via zirconocene-mediated cross-coupling of alkynylphosphines

DOI: 10.1016/j.tetlet.2004.01.098

Source and publish data:

Tetrahedron Letters p. 2427 - 2429 (2004)

Update date:2022-08-11

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Authors:

Xi, Zhenfeng

Zhang, Wenxiong

Takahashi, Tamotsu

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Article abstract of DOI:10.1016/j.tetlet.2004.01.098

Stereodefined butadienyl phosphines and related derivatives were readily prepared in high yields with perfect regioselectivity via the zirconocene-mediated pair-selective coupling of alkynylphosphines with ethylene or alkynylphosphines with normal alkynes

Full text of DOI:10.1016/j.tetlet.2004.01.098

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