Journal of Organometallic Chemistry p. C6 - C8 (1994)
Update date:2022-08-25
Topics:
Zapata, Antonio J.
Ruiz, Jacqueline
The palladium-catalyzed coupling reaction of 1-propenyltributyltin with functionalized styryl bromides is described. 1,3-Dienes are obtained in low to moderate yields except with β,β-dibromostyrene.The latter undergoes a novel organotin-promoted dehydrobromination-coupling sequence to give a 1,3-enyne as final product.Key words: Tin; Palladium; Styryl bromide; Coupling reaction; Bromides; Catalysis
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