Journal of the American Chemical Society
Communication
(14) Simmons, E. M.; Hartwig, J. F. Angew. Chem., Int. Ed. 2012, 51,
3066.
ACKNOWLEDGMENTS
■
We acknowledge generous start-up funds from Indiana
University in partial support of this work. We also gratefully
acknowledge the American Chemical Society Petroleum
Research Fund (PRF52233-DNI1) and Eli Lilly & Co. for
the Lilly Grantee Award used to support this work. We would
also like to thank Prof. Gojko Lalic for insightful discussions on
kinetics.
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(12) For Pd examples of cross reactivity with aryl iodides, see ref 2f.
For Fe examples of cross reactivity with aryl iodides, see refs 7b and
7g.
(13) Similar yields among the oxygen-based electrophiles might
suggest in situ formation of benzyl bromides under the reaction
conditions.
D
dx.doi.org/10.1021/ja506823u | J. Am. Chem. Soc. XXXX, XXX, XXX−XXX