Vinylic Organoboranes. 6. A General Synthesis of (E)-Disubstituted Alkenes or Ketones via the (E)-(1-Substituted-1-alkenyl)boronic Esters

DOI: 10.1021/jo00376a041

Source and publish data:

Journal of Organic Chemistry p. 5270 - 5276 (1986)

Update date:2022-08-11

Topics:

Authors:

Brown, Herbert C.

Basavaiah, D.

Kulkarni, Surendra U.

Lee, Hsiupu D.

Negishi, Ei-ichi

Katz, Jean-Jacques

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Article abstract of DOI:10.1021/jo00376a041

Development of a general stereospecific synthesis of (E)-disubstituted alkenes utilizing a variety of hydroborating agents such as monohaloborane, thexylborane, thexylchloroborane, and dibromoborane is discussed.Hydroboration of 1-halo-1-alkynes with dial

Full text of DOI:10.1021/jo00376a041

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