A short and efficient synthesis of (3E,5Z)-1,3,5-undecatriene from (1E)- 1-chloro-1,3-butadiene

Article abstract of DOI:10.1080/00397919408019052

A short synthesis of (3E,5Z)-1;3,5-undecatriene (cis-galbanolene) is described. The key step is the Pd/Cu-catalyzed coupling reaction of (E)-1- chloro-1,3-butadiene with 1-alkynes followed by stereoselective zinc reduction of the triple bond.

Full text of DOI:10.1080/00397919408019052

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Synthetic Communications: An
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A Short and Efficient Synthesis
of (3E,5Z)-1,3,5-Undecatriene
from (1E)-1-Chloro-1,3-
butadiene
Chanh Huynh a , Mou[acaron]d Alami a & Gérard
Linstrumelle a
a Laboratoire de Chimie , Ecole Normale
Supérieure , 24, Rue Lhomond 75231, Paris, Cedex,
05, France
Published online: 23 Sep 2006.
To cite this article: Chanh Huynh , Mou[acaron]d Alami & Gérard Linstrumelle
(1994) A Short and Efficient Synthesis of (3E,5Z)-1,3,5-Undecatriene from (1E)-1-
Chloro-1,3-butadiene, Synthetic Communications: An International Journal for
Rapid Communication of Synthetic Organic Chemistry, 24:16, 2273-2280, DOI:
10.1080/00397919408019052
To link to this article: http://dx.doi.org/10.1080/00397919408019052
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