Tetrahedron Letters p. 8415 - 8418 (1993)
Update date:2022-08-17
Topics:
Garcia-Garibay, Miguel A.
Theroff, Craig
Shin, Steve H.
Jernelius, Jesper
Results from intramolecular singlet and triplet specific reactivity in solvents of different polarity suggest that the spin state equilibrium of 1,2-diphenyl-1-butylidene, a triplet ground state carbene, is largely susceptible to solvent polarity.The results are consistent with stabilization of the zwitterionic singlet state in solvents of high polarity.
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Doi:10.1021/acs.orglett.6b03244
(2016)Doi:10.1021/ja01103a019
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