C. Monnereau, J.-N. Rebilly, O. Reinaud
FULL PAPER
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floppy as dodecyldiamine.[35] Our hope is that the concepts
introduced in this article, namely the possibility of preor-
ganizing thermodynamically and kinetically a substrate
(mimicked by the amine in this study, but could be an
alcohol, an amide, or a nitrile) next to a potentially reactive
center (here, the metalloporphyrin) owing to the direction-
ality inherent to a calixarene host, will be exploitable for
the development of efficient site-selective catalysts based on
a similar framework. The synthesis and examination of the
catalytic properties of a (Mn)porphyrin analogue of our
system, Calix(Zn)P(Mn), are currently under investigation.
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Experimental Section
For experimental details see the Supporting Information.
Supporting Information (see also the footnote on the first page of
this article): Synthetic procedures, characterization of products and
complexes, NMR and UV/Vis titrations and other experimental
details.
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Acknowledgments
We thank O. Gimello and Dr. D. Touboul (Institut de Chimie des
Substances Naturelles, UPR CNRS 2301, Gif-sur-Yvette, France)
for HRMS analysis of our Zn complexes.
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