Two-carbon extension of N,N-disubstituted amides with bis(trimethylsilyl) thioketene affording N,N-disubstituted 3-oxothioamides

DOI: 10.1039/cc9960001621

Source and publish data:

Chemical Communications p. 1621 - 1622 (1996)

Update date:2022-08-10

Topics:

Authors:

Tsuchiya, Tohru

Oishi, Akihiro

Shibuya, Isao

Taguchi, Yoichi

Honda, Kazumasa

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Article abstract of DOI:10.1039/cc9960001621

N,N-Disubstituted alkanamides cleanly react with bis(trimethylsilyl)thioketene to form N,N-disubstituted 2-trimethylsilyl-3-trimethylsilyloxyalk-2-enethioamides, which upon acid hydrolysis give N,N-disubstituted 3-oxoalkanethioamides.

Full text of DOI:10.1039/cc9960001621

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