ENE-REACTIVITE D'ALLYLSILANES: FONCTIONNALISATION ET REGIOCHIMIE

Article abstract of DOI:10.1016/0022-328X(85)87104-7

The hydroperoxidation of various allylsilanes by singlet oxygen has been studied.The regioselectivity of this reaction compared to those of ethyl azodicarboxylate and 4-phenyl-1,2,4-triazoline-3,5-dione, is discussed.Mechanisms are considered in the general field of the ene reaction applied to allylic organometallic Group IVB compounds.The structures of the new products (alcohols, urazoles, hydrazines) have been determined, directly or after transformations, by NMR spectroscopy.