2,4,6-TRI-t-BUTYLPHENYLLITHIUM AS A BASE-----KINETIC DEPROTONATION OF BENZYL METHYL KETONE

DOI: 10.1016/S0040-4039(01)91364-4

Source and publish data:

Tetrahedron Letters p. 6325 - 6328 (1987)

Update date:2022-08-10

Topics:

Authors:

Yoshifuji, Masaaki

Nakamura, Tetsuo

Inamoto, Naoki

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Article abstract of DOI:10.1016/S0040-4039(01)91364-4

An extremely bulky lithium reagent, 2,4,6-tri-t-butylphenyllithium, was applied for deprotonation of benzyl methyl ketone to give the kinetic enol ether by "in situ" quenching with chlorotrimethylsilane as the major product indicating that the reagent serves as a hindered base.

Full text of DOI:10.1016/S0040-4039(01)91364-4

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