Helvetica Chimica Acta p. 1618 - 1626 (1989)
Update date:2022-08-25
Topics:
Mueller, Paul
Bernardinelli, Gerald
Jacquier, Yvan
Ricca, Alessandra
Reaction of 1H-cyclopropanaphthalene (1a) or 1H-cycloporpaanthracene (10a) with tris(acetonitrile)tricarbonylchromium affords cyclobutanaphthalenone and cyclobutaanthracenone 2 and 11, respectively.In contrast, the bis-silylated cycloproparenes 1b and 10b undergo complexation at the terminal benzene ring and lead to the arene-tricarbonylchromium complexes 4b and 12, respectively.Desilylation of 4b to 4a is effected by t-BuOK.
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