Journal of the American Chemical Society p. 2516 - 2518 (1982)
Update date:2022-08-11
Topics:
Allen, Annette D.
Shahidi,, Fereidoon
Tidwell, Thomas T.
The reactivities of 1-cyano-1-ethoxyethylene (1) and 1-(trifluoromethyl)-1-ethoxypentene (2) in aqueous H2SO4 and D2SO4 have been measured.The kinetics and products establish the mechanism of these reactions as rate-limiting protonation on the double bond.The observed rates are predicted with surprising accuracy by the previously introduced correlation logkH+ = -10.5Σp+ - 8.92.
View MoreChongqing Acme Tech. Co., Ltd.
Contact:+86-23-89118971
Address:2501 Huachuang Bldg., No.10 Red-yellow Road, Jiangbei
Hangzhou Bayee Chemical Co.,Ltd.
Contact:+86-571-86990109
Address:No.380, Jiangnan Auenue, Binjiang District, Hangzhou, China
Qingdao Kylin Trading Co., Ltd.
Contact:0086-532-68979884/58972912/68972263/65/88171519
Address:Room 2308,A building International Trade Center No.230 Changjiang Middle Road of Qingdao Economic Development Zone,Shandong,China.
Jiaozuo Zhongwen Trading Coporation Limited
Contact:+86 0391-3553810
Address:East Renmin Road
Suzhou Time-chem Technologies Co., Ltd.
Contact:0512-63983931/68086856
Address:No. 1326 of Binhe Road, New District, Suzhou, Jiangsu, P. R. China
Doi:10.1021/acs.inorgchem.7b02812
(2018)Doi:10.1039/c5ra24563j
(2016)Doi:10.1016/j.catcom.2019.01.006
(2019)Doi:10.1039/c6nj00321d
(2016)Doi:10.1002/jccs.202000075
(2020)Doi:10.1016/j.bmc.2017.05.052
(2017)