A practical synthesis of β-keto phosphonates from triethyl phosphonoacetate

Article abstract of DOI:10.1080/00397919608004561

An efficient and practical preparation of β-keto phosphonates, via acylation reaction of triethyl phosphonoacetate with carboxylic acid chlorides in the presence of magnesium chloride-triethylamine followed by decarbethoxylation, is described.

Full text of DOI:10.1080/00397919608004561

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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A Practical Synthesis of β-Keto
Phosphonates from Triethyl
Phosphonoacetate
Dae Young Kim a , Myeon Sik Kong a & Taek Hyeon
Kim b
a Department of Chemistry, Soonchunhyang
University, Onyang P. O. Box 97, Chungnam,
336-600, Korea
b Department of Fine Chemical Technology,
Chonnam National University, Kwangju, 500-757,
Korea
Version of record first published: 23 Aug 2006.
To cite this article: Dae Young Kim, Myeon Sik Kong & Taek Hyeon Kim (1996): A
Practical Synthesis of β-Keto Phosphonates from Triethyl Phosphonoacetate, Synthetic
Communications: An International Journal for Rapid Communication of Synthetic
Organic Chemistry, 26:13, 2487-2496
To link to this article: http://dx.doi.org/10.1080/00397919608004561
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