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4 For non-enantioselective methods for carbonyl isoprenylation, see:
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to the stereoselective modification of unprotected diols and
chiral a-stereogenic alcohols. Studies toward amphidinolide V
via asymmetric alcohol-mediated carbonyl isoprenylation are
presently underway.
The Welch Foundation (F-0038) and the NIH (RO1-GM069445)
are acknowledged for partial support of this research. The China
Scholarship Council is acknowledged for research internship
scholarship support (G. L. CGC.201707060020).
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Conflicts of interest
8 (a) Z. Zhang, H. Xie, H. Li, L. Gao and Z. Song, Org. Lett., 2015,
17, 4706; (b) K. Mori and M. Ikunaka, Tetrahedron, 1984, 40, 3471.
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154, 509; (b) N. Torbjoern, Pure Appl. Chem., 1989, 61, 547;
(c) Q.-H. Zhang, G. Birgersson, F. Schlyter and G.-F. Chen, J. Chem.
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There are no conflicts to declare.
Notes and references
1 For recent reviews on alcohol-mediated carbonyl addition, see:
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2 For application of alcohol-mediated carbonyl addition in natural product
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