Negative-ion mass spectrometry of carbohydrates. A mechanistic study of the fragmentation reactions of dideoxy sugars

Article abstract of DOI:10.1080/07328309608005697

Hydroxyl group deprotonation of the a and β anomers of methyl 3-O-benzyl-2,6-dideoxy-D-arabino-hexopyranoside (1 and 2) occurs readily in the gas phase to produce the corresponding anions 3 and 4, respectively. Collisionally activated dissociation (CAD) o

Full text of DOI:10.1080/07328309608005697

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Journal of Carbohydrate Chemistry
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Negative-Ion Mass Spectrometry of
Carbohydrates. A Mechanistic Study of
the Fragmentation Reactions of Dideoxy
Sugars
Roger W. Binkley a b , Edith R. Binkley b , Shaoming Duan a , Michael
J. S. Tevesz a & Witold Winnik a
a Department of Chemistry , Cleveland State University , Cleveland,
Ohio, 44115
b Center For Carbohydrate Study , 19 Hawthorne Dr. Oberlin, Ohio,
44074
Published online: 22 Aug 2006.
To cite this article: Roger W. Binkley , Edith R. Binkley , Shaoming Duan , Michael J. S. Tevesz &
Witold Winnik (1996) Negative-Ion Mass Spectrometry of Carbohydrates. A Mechanistic Study of the
Fragmentation Reactions of Dideoxy Sugars, Journal of Carbohydrate Chemistry, 15:7, 879-895, DOI:
10.1080/07328309608005697
To link to this article: http://dx.doi.org/10.1080/07328309608005697
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