Conversion of Fluorocarbon Olefins into Perfluoro-ketoximes

Article abstract of DOI:10.1016/S0022-1139(00)85245-8

Treatment of perfluoro-2-nitrosopropane and perfluoronitrosocyclobutane with aqueous potassium bisulphite yields the oximes of perfluoroacetone and perfluorocyclobutanone, respectively; the nitroso-compounds are easily prepared via indirect addition of nitrosyl fluoride across the double bonds in perfluoropropene and perfluorocyclobutene.