CH2OH + O2 reaction rate constant measured by detecting HO2 from photofragment emission

Article abstract of DOI:10.1063/1.448015

The HO2 radical was produced in a flow tube by the Cl + CH3OH <*> HCl + CH2OH and CH2OH + O2 <*> HO2 + CH2O reactions.HO2 was detected by the OH(A²Σ⁺ <*>X²Π) photofragment emission produced by photodissociative excitation of HO2 in the vacuum ultraviolet region.Using this detection method, the rate constant for the CH2OH and O2 reaction was measured to be ( 1.4+/-0.4) X 10^-12 cm³/s.

Full text of DOI:10.1063/1.448015

CH2OH+O2 reaction rate constant measured by detecting HO2 from photofragment
emission
W. C. Wang, Masako Suto, and L. C. Lee
Citation: The Journal of Chemical Physics 81, 3122 (1984); doi: 10.1063/1.448015
View online: http://dx.doi.org/10.1063/1.448015
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/81/7?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
41.209.100.60 On: Mon, 22 Dec 2014 10:02:18
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
41.209.100.60 On: Mon, 22 Dec 2014 10:02:18
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
41.209.100.60 On: Mon, 22 Dec 2014 10:02:18
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
41.209.100.60 On: Mon, 22 Dec 2014 10:02:18
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
41.209.100.60 On: Mon, 22 Dec 2014 10:02:18
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