Journal of Chemical Physics p. 3122 - 3126 (1984)
Update date:2022-08-16
Topics:
Wang, W. C.
Suto, Masako
Lee, L. C.
The HO2 radical was produced in a flow tube by the Cl + CH3OH <*> HCl + CH2OH and CH2OH + O2 <*> HO2 + CH2O reactions.HO2 was detected by the OH(A2Σ+ <*>X2Π) photofragment emission produced by photodissociative excitation of HO2 in the vacuum ultraviolet region.Using this detection method, the rate constant for the CH2OH and O2 reaction was measured to be ( 1.4+/-0.4) X 10-12 cm3/s.
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