Tetrahedron Letters p. 6745 - 6748 (1996)
Update date:2022-08-11
Topics:
Nara, Shinji
Toshima, Hiroaki
Ichihara, Akitami
A new approach for the construction of the hydrindane framework has been achieved by intramolecular 1,6-conjugate addition under some basic conditions. The precursors, α, β, γ, δ-unsaturated esters (11a-11d) were synthesized from the ester 8 and acrolein derivatives (6a-6d) via aldol condensation. This methodology was applied to the total synthesis of (±)-coronafacic acid and its analogues.
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