Journal of Organic Chemistry p. 2424 - 2427 (1993)
Update date:2022-08-17
Topics:
Savion, Zeev
Wernick, David L.
The photodimerization of trans-p-bromocinnamic acid, possessing a stack crystal structure in which each monomer has two monomeric nearest neighbors in the stack dimension, was monitored by FTIR spectroscopy.Upon UV irradiation, FTIR spectral shifts and transient absorptions indicated that residual monomers were present in altered crystal-structure environments.The results are interpreted according to a kinetic model in which monomers have one or two dimeric nearest neighbors at intermediate levels of photoconversion.
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