Journal of the Chemical Society. Chemical communications p. 1267 - 1268 (1981)
Update date:2022-08-30
Topics:
Matsumoto, Shigenobu
Matsuo, Mitsuyoshi
Iitaka, Yoichi
The potassium t-butoxide-catalysed oxygenation of an α-tocopherol model compound, 2,2,5,7,8-pentamethylchroman-6-ol, gave 5-hydroxy-2,2,5,7,8-pentamethylchroman-6(5H)-one (2) and 7,8-dihydro-5,7-dihydroxy-8-methylene-2,2,5,7-tetramethylchroman-6(5H)-one, and 6-hydroxy-2,2,6,7,8-pentamethylchroman-5(6H)-one which was found to be formed as the result of the acyloin rearrangement of (2).
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Doi:10.1007/BF00854459
()Doi:10.1039/b506735a
(2005)Doi:10.1007/s10600-011-9838-z
(2011)Doi:10.1002/pola.24532
(2011)Doi:10.1021/jf503060k
(2014)Doi:10.1016/S0022-1139(00)81494-3
(1983)
