A β,β-Shielded Vinyllithium Example for a Quantification of Structure, Monomer-Dimer Equilibrium, and some Reactivity Parameters

DOI: 10.1016/S0040-4020(01)90440-5

Source and publish data:

Tetrahedron p. 5845 - 5860 (1994)

Update date:2022-08-29

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Authors:

Knorr, Rudolf

Freudenreich, Johannes

Polborn, Kurt

Noeth, Heinrich

Linti, Gerald

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Article abstract of DOI:10.1016/S0040-4020(01)90440-5

Key Words: Aggregation, crystal structure, lithiation, organolithium compounds, reactivity.Crystalline 2-(lithiomethylene)-1,1,3,3-tetramethylindan (3) forms the etherate 11 as a centrosymmetric dimer with a LiCLiC four-membered ring.The carbanionic termi

Full text of DOI:10.1016/S0040-4020(01)90440-5

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