107740-09-0

Basic information

• Product Name: 1,4:3,6-dianhydromannitol di-p-toluenesulfonate
• CAS NO: 107740-09-0
• Molecular Weight: 454.522
• Mol File: 107740-09-0.mol

Chemical Properties

• CAS DataBase Reference: 1,4:3,6-dianhydromannitol di-p-toluenesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4:3,6-dianhydromannitol di-p-toluenesulfonate(107740-09-0)
• EPA Substance Registry System: 1,4:3,6-dianhydromannitol di-p-toluenesulfonate(107740-09-0)

Safety Data

• Hazardous Substances Data: 107740-09-0(Hazardous Substances Data)

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 641-74-7 1,4:3,6-dianhydro-D-mannitol 
• 69-65-8 mannitol 
• 82064-06-0 1,4:3,6-dianhydro-2,5-di-O-benzoyl-D-mannitol 
• 652-67-5 Isosorbide 
• 641-74-7 1,4:3,6-dianhydro-L-iditol 
• 24808-18-2 di-O-acetyl-1,4;3,6-dianhydro-L-iditol 
• 54522-28-0 (3R,3aS,6R,6aS)-hexahydrofuro[3,2-b]furan-3,6-diyl bis(4-methylbenzenesulfonate) 
• 53648-56-9 3,6-anhydro-D-glucitol 
• 50-70-4 D-sorbitol 

Downstream Products

• 641-74-7 1,4:3,6-dianhydro-D-mannitol 
• 48107-55-7 2,5-diamino-1,4:3,6-dianhydro-2,5-dideoxy-L-iditol,DAI 
• 24808-18-2 di-O-acetyl-1,4;3,6-dianhydro-L-iditol 
• 1002123-62-7 (3R,3aS,6aS)-6-iodohexahydrofuro[3,2-b]furan-3-yl 4-methylbenzenesulphonate 
• 3770-77-2 (1R,4R,5R,8S)-(+)-4,8-Diiodo-2,6-dioxabicyclo<3.3.0>octane 
• 3770-77-2 (1R,4S,5R,8S)-(+)-4,8-Diiodo-2,6-dioxabicyclo<3.3.0>octane 
• 953048-51-6 (3S,3aR,6S,6aR)-N,N'-dibenzylhexahydrofuro[3,2-b]furan-3,6-diamine 
• 641-74-7 1,4:3,6-dianhydro-L-iditol 
• 54522-28-0 1,4:3,6-dianhydro-2,5-di-O-p-tosyl-D-iditol 
• 55199-75-2 1,4:2,5:3,6-trianhydro-D-mannitol 
• 652-67-5 Isosorbide 
• 1195674-49-7 O²-acetyl-O⁵-(toluene-4-sulfonyl)-1,4;3,6-dianhydro-L-iditol 
• 3720-08-9 (1S,4S,5R,8S)-(+)-8-Iodo-4-(p-toluenesulfonyloxy)-2,6-dioxa<3.3.0>octane 
• 48107-55-7 (3R,3aR,6S,6aR)-hexahydrofuro[3,2-b]furan-3,6-diamine 

Relevant articles and documents

Synthesis and structure of 1,4:3,6-dianhydro-2-O-p-tosyl-D-mannitol

1,4:3,6-Dianhydro-2-O-p-tosyl-D-mannitol (3) has been isolated from the reaction of 1,4:3,6-dianhydro-D-mannitol (2) and p-toluenesulfonyl chloride (1:2 mole ratio) in pyridine in 19% yield after fractional crystallization. It crystallizes in the orthorhombic space group P212121 (Z = 4) with a = 6.064(2), b = 8.347(1) and c = 26.455(16) A. Disorder associated with the unsubstituted furanose ring provides two arrangements, rings B and C, with two sets of sites for both the hydroxyl group and a ring carbon atom: the relative occupancy of ring B: ring C = 0.53(1):0.47(1). Distinct H-bonding situations (both intra- and inter-molecular) are associated with the two arrangements. The conformations of the unsubstituted furanose ring with the weaker intramolecular H-bonding (ring B) and the tosyl-substituted ring (ring A) are very similar, being 1:2 mixtures of envelope [3E] and twist forms [3T4]: the stronger H-bonding in ring C results instead in a conformation made up from a 30:70 mixture of E0 and 4T0 forms. The 1H-NMR spectrum for 3 indicates that the average solution conformation is also a mixture of envelope and twist forms and is similar to that of the A/B solid-state arrangement.

Structure-properties relationship of biosourced stereocontrolled polytriazoles from click chemistry step growth polymerization of diazide and dialkyne dianhydrohexitols

The design of dialkyne and diazide functionalized dianhydrohexitol stereoisomers (1-6) afforded a new family of starch-based polytriazoles (7-15) with defined stereochemistry through A2 + B2 CuAAC step growth polymerization. The pres

Partially bio-based polyimides from isohexide-derived diamines

Abstract Novel partially bio-based polyimides were prepared from 2, 5-diamino-2, 5-dideoxy-1, 4: 3, 6-dianhydrosorbitol (diaminoisosorbide, DAIS) dihydrochloride, 2, 5-diamino-2, 5-dideoxy-1, 4: 3, 6-dianhydroiditol (diaminoisoidide, DAII) dihydrochloride

Novel, fully biobased semicrystalline polyamides

Novel, semicrystalline polyamides and co(polyamides) were synthesized from biobased sebacic acid (SA), 2,5-diamino-2,5-dideoxy-1,4;3,6-dianhydroiditol (diaminoisoidide, DAII) as well as from 1,4-diaminobutane (DAB), also known as putrescine in nature. Low

Chiral silver and gold rings: Synthesis and structural, spectroscopic, and photophysical properties of Ag and Au metallamacrocycles of bridging NHC ligands

The synthesis and silver(I) and gold(I) coordination chemistry of a new chiral, bidentate N-heterocyclic carbene (NHC) dehydrohexitol derivative (3) are reported. The imidazolium salt [H23][PF6]2 reacts with Ag2

NOVEL AZABENZIMIDAZOLE HEXAHYDROFURO[E,2-B]FURAN DERIVATIVES

Novel compounds of the structural formula (I) are activators of AMP-protein kinase and may be useful in the treatment, prevention and suppression of diseases mediated by the AMPK activated protein kinase. The compounds of the present invention may be usef

MONOFLUORINATED DERIVATIVES OF DIANHYDROHEXITOLS AND PROCESSES FOR MAKING THE SAME

Novel monofluoro analogs of isosorbide, isomannide and isoidide are described, together with processes for making such monofluoro analogs.

Dianhydrohexitols: New tools for organocatalysis. Application in enantioselective Friedel-Crafts alkylation of indoles with nitroalkenes

A series of hydrogen bonding organocatalysts was synthesized from dianhydrohexitol and was used for the first time in organocatalysis for Friedel-Crafts alkylation of indoles with nitroalkenes. Moderate yields and enantioselectivities were achieved. ARKAT

Renewable rigid diamines: Efficient, stereospecific synthesis of high purity isohexide diamines

We report an efficient three-step strategy for synthesizing rigid, chiral isohexide diamines derived from 1,4:3,6-dianhydrohexitols. These biobased chiral building blocks are presently the subject of several investigations (in our and several other groups

New chiral imidazolium ionic liquids from isomannide

New chiral bis and mono-imidazolium ionic liquids derived from isomannide were synthesized. The structural features of the chiral organic cations impart a special arrangement of the chiral cavity. The new chiral chloride salts of isomannide derivatives ar