Erratum: Removal of the E-Olefin Barrier of Humulene Leading to Unnatural Terpenoid-like Skeletons (Organic Letters (2018) 20, 22, (7313-7320) DOI: 10.1021/acs.orglett.8b03259)

Article abstract of DOI:10.1021/acs.orglett.9b00264

The structures of compounds 11 and 12 shown in Figure 2A were corrected by changing the relative configurations, although the structures in the Supporting Information were correct. Figure 2A is corrected as follows: The absolute configurations of compounds 15-19 drawn in Figure 3A and in the Supporting Information were corrected. Although the relative configurations shown in the Supporting Information were correct, the wrong assignment is because of drawing the absolute configuration at the C-6 position of 15- 17 in reverse. The corrected Figure 3A is as follows and and the revised Supporting Information with the corrected structures for compounds 15-17 is included with this Correction.

Full text of DOI:10.1021/acs.orglett.9b00264

Addition/Correction
pubs.acs.org/OrgLett
Cite This: Org. Lett. XXXX, XXX, XXX−XXX
Correction to “Removal of the E‑Olefin Barrier of Humulene Leading
to Unnatural Terpenoid-like Skeletons”
Takehiro Nishimura, Junya Kawai, Yoshiteru Oshima, and Haruhisa Kikuchi*
Org. Lett. 2018, 20 (22), 7313−7320. DOI: 10.1021/acs.orglett.8b03259
*
S Supporting Information
The structures of compounds 11 and 12 shown in Figure 2A
were corrected by changing the relative configurations,
although the structures in the Supporting Information were
correct. Figure 2A is corrected as follows:
ASSOCIATED CONTENT
Supporting Information
■
*
S
The Supporting Information is available free of charge on the
ACS Publications website at DOI: 10.1021/acs.or-
glett.9b00264.
General experimental procedures, detailed experimental
procedures, and characterization data for all new
compounds (PDF)
Figure 2. (A) Synthesis of unnatural terpenoid-like compounds 9−
12.
The absolute configurations of compounds 15−19 drawn in
Figure 3A and in the Supporting Information were corrected.
Although the relative configurations shown in the Supporting
Information were correct, the wrong assignment is because of
drawing the absolute configuration at the C-6 position of 15−
17 in reverse. The corrected Figure 3A is as follows and and
the revised Supporting Information with the corrected
structures for compounds 15−17 is included with this
Correction.
Figure 3. (A) Synthesis of salvialane-type compounds 15−17.
Received: January 22, 2019
©
XXXX American Chemical Society
A
DOI: 10.1021/acs.orglett.9b00264
Org. Lett. XXXX, XXX, XXX−XXX