Dalton Transactions p. 13081 - 13087 (2018)
Update date:2022-08-17
Topics:
Amaral, Ronaldo C.
Murakami Iha, Neyde Y.
Novel fac-[Re(CO)3(dmcb)(trans-stpyR)]+ complexes, dmcb = 4,4′-dimethoxycarbonyl-2,2′-bipyridine, have been judiciously engineered to absorb at lower energies and sensitize trans-4-styrylpyridine (trans-stpy) or trans-4-(4-cyano)styrylpyridine (trans-stpyCN) photoisomerizable ligands up to 436 nm of irradiation. Moreover, these complexes exhibit remarkable photoreversibility, in particular fac-[Re(CO)3(dmcb)(trans-stpyCN)]+ (Φ255 nmcis→trans = 0.26 ± 0.02). Their distinct and noteworthy photochemical and photophysical behavior are described in this work. The main emphasis of this study is that the complexes efficiently sensitize stilbene-like ligand isomerization toward use in potential solar device applications.
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Doi:10.1021/acs.bioconjchem.7b00828
(2018)Doi:10.1016/S0957-4166(01)00446-3
(2001)Doi:10.1023/A:1011029226072
(2001)Doi:10.1021/acs.orglett.5b02715
(2015)Doi:10.1039/a803477j
(1998)Doi:10.3390/molecules22040633
(2017)