Tetrahedron Letters p. 2237 - 2240 (1985)
Update date:2022-08-17
Topics:
Wassermann, Harry H.
Pearce, Bradley C.
Racemic anhydrocannabisativine has been efficiently synthesized by employing a β-lactam-imino ether coupling reaction.The key to the formation of the tetrahydropyridine moiety of the natural alkaloid is a stereoselective intramolecular conjugate addition of a secondary amino group to a Z,E dienone.
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