Tris(dibenzylideneacetone)dipalladium(0)

Base Information Edit

Chemical Name:Tris(dibenzylideneacetone)dipalladium(0)
CAS No.:51364-51-3
Molecular Formula:C51H42O3Pd2
Molecular Weight:915.733
Hs Code.:28439000
European Community (EC) Number:610-654-4,620-687-6,932-667-7
Wikipedia:Tris(dibenzylideneacetone)dipalladium(0)
Mol file:51364-51-3.mol

Synonyms:tris(dibenzylideneacetone)dipalladium;Tris-DBA

Suppliers and Price of Tris(dibenzylideneacetone)dipalladium(0)

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Tris(dibenzylideneacetone)dipalladium
10g
$ 290.00

TCI Chemical
Tris(dibenzylideneacetone)dipalladium(0) >75.0%(T)
5g
$ 412.00

TCI Chemical
Tris(dibenzylideneacetone)dipalladium(0)
200MG
$ 23.00

TCI Chemical
Tris(dibenzylideneacetone)dipalladium(0) >75.0%(T)
1g
$ 83.00

Strem Chemicals
Tris(dibenzylideneacetone)dipalladium(0)
5g
$ 275.00

Strem Chemicals
Tris(dibenzylideneacetone)dipalladium(0)
1g
$ 69.00

Strem Chemicals
Tris(dibenzylideneacetone)dipalladium(0)
25g
$ 1103.00

Sigma-Aldrich
Tris(dibenzylideneacetone)dipalladium(0) 97%
500g
$ 7710.00

Sigma-Aldrich
Tris(dibenzylideneacetone)dipalladium(0) 97%
100g
$ 3130.00

Sigma-Aldrich
Tris(dibenzylideneacetone)dipalladium(0) 97%
50g
$ 1150.00

Total 164 raw suppliers

Chemical Property of Tris(dibenzylideneacetone)dipalladium(0) Edit

Chemical Property:

Appearance/Colour:dark purple solid
Melting Point:152-155 °C
Boiling Point:400.7 °C at 760 mmHg
Flash Point:176.2 °C
PSA：51.21000
LogP:10.47090
Storage Temp.:2-8°C
Sensitive.:Air & Moisture Sensitive
Solubility.:Soluble in chlorinated solvents, benzene and THF.
Water Solubility.:insoluble
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:12
Exact Mass:916.12077
Heavy Atom Count:56
Complexity:272

Purity/Quality:

99% ^*data from raw suppliers

Tris(dibenzylideneacetone)dipalladium ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xn
Hazard Codes:Xn
Statements: 20/22-36-40
Safety Statements: 24/25-36/37

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.[Pd].[Pd]
Isomeric SMILES:C1=CC=C(C=C1)/C=C/C(=O)/C=C/C2=CC=CC=C2.C1=CC=C(C=C1)/C=C/C(=O)/C=C/C2=CC=CC=C2.C1=CC=C(C=C1)/C=C/C(=O)/C=C/C2=CC=CC=C2.[Pd].[Pd]
Description Tris(dibenzylideneacetone) dipalladium (Tris DBA) is used as catalyst for a wide variety of Pd catalyzed reactions including Suzuki coupling, Heck coupling, Negishi coupling, Carroll reaarangement, Trost asymmetric allylic alkylation, Buchwald-Hartwig amination of acryl halides, fluorination of allylic chlorides, arylation of ketones, carbonylation of 1,1-dichloro-1-alkenes, ?-arylation of carboxylic esters, and conversion of aryl and vinyl triflates to aryl and vinyl halides. It is also involved in the synthesis of azepane. Tris DBA is also a novel inhibitor of N-myristoyltransferase-1 with significant antitumor activity.
Uses Tris(dibenzylideneacetone)dipalladium is used in the preparation of semiconducting polymers processed from nonchlorinated solvents into high performance thin film transistors. Also used in the synthesis of polymer bulk-heterojunction solar sells as a semiconductor. suzuki reaction A cycloaddition catalyst.

Technology Process of Tris(dibenzylideneacetone)dipalladium(0)

There total 3 articles about Tris(dibenzylideneacetone)dipalladium(0) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.3%